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Create a New profile
Enter a name for the profile.
Select Certificates from the left bar, then “Configure”
Select (multiple) pfx/PKCS12 files to include in the profile.
(Optionally) set the PKCS12 passwords
Save and export to devices (e.g. via AirPlay)
On the device, go to Settings and accept the profile
In the Settings app, go to Mail/Accounts
Edit all the mailboxes to which you want to assign certificates.
Under Account/Advanced
Activate the Sign option and select the certificate
Tap Encrypt by Default and select the certificate again. Leave Encrypt by Default unchecked!